The colour of transition metal ions is attributed to :
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The colour of the compounds of transition metals may be attributed to the presence of incomplete (n – 1) d-sub-shell. Under the influence of approaching ions towards the central metal ion, the d-orbitals of the central metal split into different energy levels. This phenomenon is called crystal field splitting. In the case of the transition metal ions, the electron can be easily promoted from one energy level to another in the same d-sub-shell. These are called d-d transitions. The amount of energy required to excite some of the electrons to higher energy states within the same d-sub-shell corresponds to energy of certain colours of visible light. Therefore, when white light falls on a transition metal compound, some of its energy corresponding to a certain colour, is absorbed and the electron gets raised from lower energy set of orbitals to higher energy set of orbitals.
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